The thief of Orange Town
The first time she sees Luffy, she calls him boss in front of Buggy's thugs and leaves him to deal with them alone. In Orange Town, Nami wants to steal Buggy the Clown's map of the Grand Line. To get close, she pretends to join his crew and hands over Luffy tied up. When the pirates order her to kill Luffy to prove her loyalty, she can't.
After Luffy beats Buggy, Nami takes the map and the treasure and travels on with him and Zoro, making it clear she's just a partner and not a pirate. She tells anyone who'll listen that she hates pirates and only wants their treasure.